Metallic Bonding

Metals are held together by delocalized bonds formed from the atomic orbitals of all the atoms in the lattice. The orbitals spread over many atoms and blend into a band of molecular orbitals. The range of energies of these orbitals are closely spaced. The band is composed of as many levels as there are contributing atomic orbitals and each level can hold electrons of opposite spin. The idea that the molecular orbitals of the band of energy levels are spread or delocalized over the atoms of the piece of metal accounts for bonding in metallic solids. This theory of metallic bonding is called the band theory. The band is split into two regions, the upper portion being the empty levels or the antibonding and the lower portion is the filled levels or the bonding orbitals. In a metal the band of energy levels is only partly filled. The highest filled level right before going to the empty level is called the Fermi level. The trend of melting points of the transition metals is based on the electrons in the metal.



INSTRUCTIONS:

Last modified: April 13, 2000